Outside of ensuring you have plenty of life, there are a few interesting interactions that can come from doubling your life total
The escape cost is equal to the card's mana cost plus exile three other cards from your graveyard

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Battle of Wits, as mentioned, is a specific reason to have more than 60 cards, because the alternative win condition requires more than 200 cards
To figure out the value of the Pokmon cards that you want to sell, youll want to look at their rarity symbols, Pokmon card condition, grading (if applicable), and market comparisons